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Vol 10, 2014
Pages: 11 - 19
Keynote paper
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Published: 24.04.2014. Keynote paper Keynote papers

THERMODYNAMICS AND PHASE DIAGRAMS OF GALLIUM-BASED MULTICOMPONENT SYSTEMS

By
Dragana Živković
Dragana Živković
Contact Dragana Živković

Tehnički fakultet u Boru, Univerzitet u Beogradu , Bor , Serbia

Abstract

The review of long-lasting investigations at Department of Metallurgical Engineering, Technical 
Faculty in Bor, University of Belgrade in the field of thermodynamics and phase diagrams of 
numerous gallium-based systems is presented in this paper. The results of investigation of some 
binary and ternary systems, obtained experimentally (Oelsen calorimetry, thermal analysis, optical 
microscopy, SEM-EDX), thermodynamic predicting (general solution model), as well as by phase 
diagram calculation according to CALPHAD method, are shown in this presentation. Different well 
known commercial thermodynamicsoftwares were used (Pandat,ThermoCalc). 

Funding Statement

Posebna zahvalnost Ministarstvu prosvete, nauke i tehnološkog razvoja Republike Srbije na finansijskoj pomoći u okviru projekta ON172037.

References

1.
Živković D, Manasijević D, Živković Z. Thermodynamic study of Ga-Sn and Ga-Zn systems using quantitative differential thermal analysis (2003. Journal of Thermal Analysis and Calorimetry. 74(1):85–96.
2.
Manasijević D, Živković D, Katayama I, Živković Ž. Calculation of the thermodynamic properties of the Ga-Sb-Tl liquid alloys (2005. Journal of the Serbian Chemical Society. 70(1):9–20.
3.
Katayama I, Shimazawa K, Živković D, Manasijević D, Živković Z, Yamashita H. Experimental study on gallium activity in the liquid Ga-In-Tl alloys by EMF method with zirconia solid electrolyte (2005. Thermochimica Acta. 431(1–2):138–43.
4.
Živković D, Manasijević D, Živković Ž. Comparative thermodynamic investigation of binary Ga-Bi system: Experimental determination of enthalpies of mixing and activity estimation for liquid Ga-Bi alloys (2005. Journal of Thermal Analysis and Calorimetry. 79(1):71–7.
5.
Novaković R, Živković D. Thermodynamics and surface properties of liquid Ga-X (X = Sn, Zn) alloys (2005. Journal of Materials Science. 40(9–10):2251–7.

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