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Vol 15, Issue 1, 2025
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Abstract
Metallic materials
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Abstract Metallic materials

OBTAINING OF Fe2+ FROM SPHALERITE CONCENTRATE

By
Miroslav Sokić ,
Miroslav Sokić
Contact Miroslav Sokić

Institute for Technology of Nuclear and other Mineral Raw Materials , Belgrade , Serbia

Dimitrije Anđić ,
Dimitrije Anđić

Institute for Technology of Nuclear and other Mineral Raw Materials , Belgrade , Serbia

Nikola Vuković ,
Nikola Vuković

Institute for Technology of Nuclear and other Mineral Raw Materials , Belgrade , Serbia

Ivana Jelić ,
Ivana Jelić

Institute for Technology of Nuclear and other Mineral Raw Materials , Belgrade , Serbia

Mladen Bugarčić ,
Mladen Bugarčić

Institute for Technology of Nuclear and other Mineral Raw Materials , Belgrade , Serbia

Vaso Manojlović ,
Vaso Manojlović

University of Belgrade – Faculty of Technology and Metallurgy , Belgrade , Serbia

Aleksandar Jovanović
Aleksandar Jovanović

Institute for Technology of Nuclear and other Mineral Raw Materials , Belgrade , Serbia

Abstract

Sphalerite is a sulfide zinc mineral, which also contains supporting metals such as iron, copper and lead. In this work, we dealt with the extraction of iron from sphalerite in a new oxidation system. Manganese dioxide was used as the primary oxidant, and KI was used as a secondary oxidizing agent with the aim of creating an I2/I- oxidation cycle in a sulfuric acid medium. The thoughtful characterization (X-ray diffraction - XRD, Scanning Electron Microscopy - SEM, Energy-dispersive X-ray spectroscopy - EDS) of the initial sample, as well as the precipitate formed after leaching was done. During the leaching tests, process parameters were varied.

 

Funding Statement

The authors are grateful to the Ministry of Science, Technological development and Innovation of the Republic of Serbia for financial support according to the contracts with the registration number 451-03-136/2025-03/200023.

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